14210-33-4Relevant academic research and scientific papers
Preparation and characterization of novel side-chain azobenzene polymers containing tetrazole group
Xue, Xiaoqiang,Yang, Jing,Huang, Wenyan,Yang, Hongjun,Jiang, Bibiao
, p. 61 - 70 (2015/10/19)
A novel methacrylate monomer containing azobenzene chromophore and tetrazole moiety, 4′-(2-methacryloxyethyl)methylamino-4-(5-chlorotetrazol-1-yl)azobenzene (MACA), was synthesized and polymerized to form homopolymer (PMACA) via reversible addition-fragme
A kinetic investigation of the thermal rearrangement of allyloxytetrazoles to N-allyltetrazolones
Cristiano, M. Lurdes S.,Johnstone, Robert A. W.
, p. 489 - 494 (2007/10/03)
The mechanism of the thermal rearrangement of 1-aryl-5-allyloxytetrazoles 1 to give 1-aryl-4-allyltetrazolones 2 in very high yield has been investigated through kinetic studies in one polar and one less polar solvent. The results suggest mainly a concerted [3,3] sigmatropic process, in which a partially positively charged allyl group migrates from oxygen to nitrogen, similar to the polar transition state found in the Claisen rearrangement.
Metal-assisted Reactions: Part 19. Burst Kinetics in Heterogeneous Catalytic Transfer Hydrogenolysis
Johnstone, Robert A. W.,Price, Peter J.
, p. 1069 - 1076 (2007/10/02)
Arene formation by catalytic transfer hydrogenolysis of aryloxytetrazolyl ethers in the liquid-phase shows biphasic concentration-time curves which indicate rate-limiting dissociation of heterogeneous complexes between catalyst and one of the reaction products, a tetrazolone.A dependence of catalytic reaction rate on pH and following modifications made to the catalyst are reported also.
