1421336-64-2Relevant academic research and scientific papers
ZrCl2(η-C5Me5)2-AlHCl 2·(THF)2: Efficient hydroalumination of terminal alkynes and cross-coupling of the derived alanes
Andrews, Philip,Latham, Christopher M.,Magre, Marc,Willcox, Darren,Woodward, Simon
, p. 1488 - 1490 (2013)
Stabilized AlHCl2·(THF)2 hydroaluminates RCCH with exceptional chemo-, regio- and stereoselectivity under efficient ZrCl 2(η-C5Me5)2 catalysis (2-5 mol%). The resulting vinyl alanes undergo palladium cross-coupling with a wide range of sp2 electrophiles (aryl, heteroaryl and vinyl halides/pseudohalides) in good to excellent yields. The Royal Society of Chemistry 2013.
