1421359-41-2

Upstream product

• 1421359-27-4 (2R,3S,6S)-7-(benzyloxy)-1-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-5-methyleneheptan-3-ol 
• 1421359-38-7 (2R,3S,6S)-7-(benzyloxy)-1-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-5-methyleneheptan-3-yl 2-(diethoxyphosphoryl)acetate 
• 565454-94-6 (S)-(4-(benzyloxy)-3-methyl-2-methylenebutyl)trimethylsilane 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 56850-58-9 methyl (2R)-3-(benzyloxy)-2-methylpropanoate 

Downstream Products

• 1421359-44-5 (S)-4-((S)-1-(benzyloxy)propan-2-yl)-6-((R)-1-((tert-butyldimethylsilyl)oxy)propan-2-yl)-5,6-dihydropyran-2-one 
• 1421359-47-8 (3R,4S,6S)-4-((R)-1-(benzyloxy)propan-2-yl)-6-((R)-1-((tert-butyldimethylsilyl)oxy)propan-2-yl)-3,4-dihydroxytetrahydropyran-2-one 

Relevant academic research and scientific papers

Relative stereochemical determination and synthesis of the C17-C25 δ-lactone fragment of hemicalide

Hemicalide is a novel marine metabolite polyketide distinguished by a unique mechanism of action. Because of insufficient quantities of purified material, this natural product has evaded complete stereochemical assignments. Recently, we have determined th