1421492-11-6Relevant articles and documents
Electrochemical Synthesis of Cyanoformamides from Trichloroacetonitrile and Secondary Amines Mediated by the B12Derivative
Moniruzzaman, Mohammad,Yano, Yoshio,Ono, Toshikazu,Shimakoshi, Hisashi,Shiota, Yoshihito,Yoshizawa, Kazunari,Hisaeda, Yoshio
, p. 16134 - 16143 (2021/07/19)
The B12derivative, heptamethyl cobyrinate, -mediated electrochemical synthesis of cyanoformamides has been developed. Aerobic oxygenation of the carbon-centered radical initiatedin situgeneration of the reactive acyl chloride intermediate, whic
Transition-Metal-Free Conversion of Trifluoropropanamides into Cyanoformamides through C-CF3 Bond Cleavage and Nitrogenation
Wang, Fang,Zhang, Tao,Tu, Hai-Yong,Zhang, Xing-Guo
, p. 5475 - 5480 (2017/05/24)
A new transition-metal-free transformation of trifluoropropanamides into cyanoformamides through a sequence of C-CF3 bond cleavage and nitrogenation using tert-butyl nitrite as the nitrogen source is described. The method features direct detrifluoromethylation, broad substrate scopes, and excellent selectivity control, representing a new shortcut for constructing the nitrile group involving C-CF3 σ-bond cleavage.
Unexpected zirconium-mediated multicomponent reactions of conjugated 1,3-butadiynes and monoynes with acyl cyanide derivatives
Yu, Shasha,You, Xu,Liu, Yuanhong
supporting information, p. 13936 - 13940 (2013/01/15)
Going ber(zirc): Zirconium-butadiyne complexes react with acyl cyanide derivatives through diverse reaction pathways. The complexes react with two molecules of carbamoyl cyanide to form 1,4-benzodiazepin-2-one-derivatives containing azazirconacycles. Reac
