1421636-94-3

Basic information

• Product Name: (+)-(S)-2-amino-3-phenyl-1-((1R,5S)-1,6,6-trimethyl-8-azabicyclo[3.2.1]octan-8-yl)propan-1-one
• CAS NO: 1421636-94-3
• Molecular Weight: 300.444
• Mol File: 1421636-94-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-(S)-2-amino-3-phenyl-1-((1R,5S)-1,6,6-trimethyl-8-azabicyclo[3.2.1]octan-8-yl)propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(S)-2-amino-3-phenyl-1-((1R,5S)-1,6,6-trimethyl-8-azabicyclo[3.2.1]octan-8-yl)propan-1-one(1421636-94-3)
• EPA Substance Registry System: (+)-(S)-2-amino-3-phenyl-1-((1R,5S)-1,6,6-trimethyl-8-azabicyclo[3.2.1]octan-8-yl)propan-1-one(1421636-94-3)

Safety Data

• Hazardous Substances Data: 1421636-94-3(Hazardous Substances Data)

Upstream product

• 61031-76-3 2,2-dimethyl-4-oxopentenal 

Relevant articles and documents

C-alkylation of chiral tropane- and homotropane-derived enamines

The synthesis and alkylation of chiral, nonracemic tropane- and homotropane-derived enamines is examined as an approach to enantioenriched α-alkylated aldehydes. The two bicyclic N auxiliaries, which differ by a single methylene group, give opposite senses of asymmetric induction on alkylation with EtI and provide modestly enantioenriched 2-ethylhexanal (following hydrolysis of the alkylated iminium). The observed stereoselectivity is supported by density functional studies of ethylation for both enamines.