142168-83-0

Upstream product

• 1501-26-4 methyl 4-(chlorocarbonyl)butyrate 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Downstream Products

• 134256-40-9 2-(o-bromophenyl)cyclohexane-1,3-dione 
• 1356499-18-7 methyl 4-(2-(2-bromobenzyl)-1,3-dioxolan-2-yl)butanoate 
• 1356499-19-8 C₁₉H₂₆O₅ 
• 1356499-20-1 methyl 2-ethoxy-2-(2-((2-(4-methoxy-4-oxobutyl)-1,3-dioxolan-2-yl)methyl)phenyl)cyclopropanecarboxylate 
• 15128-52-6 1,2,3,9-tetrahydro-4H-carbazol-4-one 

Relevant academic research and scientific papers

Lewis acid catalyzed intramolecular [3+2] cross-cycloaddition of donor-acceptor cyclopropanes with carbonyls: A general strategy for the construction of acetal[n.2.1] skeletons

Build a bridge: The first catalytic intramolecular [3+2] cycloaddition of monodonor-monoacceptor cyclopropanes (see scheme) provides a general and efficient strategy for construction of structurally diverse acetal[n.2.1] and 1,4-dioxygen-substituted cyclic skeletons, which are widely distributed in biologically important natural products. Copyright

NEW C-N-C BOND FORMATION REACTION USING NITROGENATION-TRANSMETALLATION PROCESS. NOVEL RING CONSTRUCTION OF INDOLE AND QUINOLINE DERIVATIVES.

Ketones and aryl or vinyl halides couple to give divinyl- or arylvinylamines in the presence of the titaniumisocyanate complex (1) and a palladium catalyst, via transmetallation of the titano imine complex (3) with aryl- or vinylpalladium bromide.