142169-81-1Relevant articles and documents
Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3 or [H(OEt2)2][B{3,5-(CF3)2C6H3}4]
Baumgarth, Hanna,Meier, Gregor,Von Hahmann, Cortney N.,Braun, Thomas
, p. 16299 - 16304 (2018)
The peroxido complexes trans-[M(4-C5F4N)(O2)(CNtBu)(PR3)2] (1: M = Rh, R = Et; 2a: M = Ir, R = iPr) can be used in the metal-mediated hydrogenation of O2. The reaction of trans-[Rh(4-C
Metal-free disproportionation of formic acid mediated by organoboranes
Chauvier, Clément,Thuéry, Pierre,Cantat, Thibault
, p. 5680 - 5685 (2016/09/04)
In the presence of dialkylboranes, formic acid can be converted to formaldehyde and methanol derivatives without the need for an external reductant. This reactivity, in which formates serve as the sole carbon and hydride sources, represents the first exam