1421745-32-5Relevant academic research and scientific papers
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water
Lee, Jia Ying,Fan, Wai Yip,Mak, Kar Hang Garvin,Leong, Weng Kee
, p. 275 - 280 (2013)
The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.
