1421832-73-6

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 449761-78-8 phenyl 2,3-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 100-44-7 benzyl chloride 

Downstream Products

• 1421832-71-4 phenylthio 2,3-di-O-benzyl-6,7-dideoxy-8-C-phenyl-α-D-manno-oct-8-ulopyranoside 
• 1421832-72-5 phenylthio 2,3-di-O-benzyl-6,7-dideoxy-8-C-phenyl-4-O-(trimethylsilyl)-α-D-manno-oct-8-ulopyranoside 
• 1421832-80-5 phenylthio 4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8-methoxy-8S-C-phenyl-α-D-manno-octopyranoside 
• 1421832-79-2 (Z)-phenylthio 4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8-C-phenyl-α-D-manno-oct-7-enopyranoside 
• 1421832-81-6 phenylthio 4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-phenyl-α-D-manno-octopyranoside 
• 850647-86-8 phenyl 2,3-di-O-benzyl-4-O-(p-methoxybenzyl)-α-D-thiomannopyranoside 
• 1421832-75-8 (E)-phenylthio 2,3-di-O-benzyl-4-O-(p-methoxybenzyl)-6,7-dideoxy-8-C-phenyl-α-D-manno-oct-6-eno-8-ulopyranoside 
• 1421832-77-0 phenylthio 2,3-di-O-benzyl-4-O-(p-methoxybenzyl)-6,7-dideoxy-8-C-phenyl-α-D-manno-oct-8-ulopyranoside 
• 1421832-82-7 1-adamantanyl 4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-phenyl-α-D-manno-octopyranoside 
• 1421832-83-8 1-adamantanyl 4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-phenyl-β-D-manno-octopyranoside 
• 1421832-84-9 (4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-C-phenyl-α-D-manno-octopyranosyl)-(1→3)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 1421832-86-1 (4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-C-phenyl-β-D-manno-octopyranosyl)-(1→3)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 1421832-87-2 methyl (4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-C-phenyl-α-D-manno-octopyranosyl)-(1→6)-2,3,4-tri-O-acetyl-α-D-glucopyranoside 
• 1421832-88-3 methyl (4,8-anhydro-2,3-di-O-benzyl-6,7-dideoxy-8S-C-phenyl-β-D-manno-octopyranosyl)-(1→6)-2,3,4-tri-O-acetyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Organotin-catalyzed regioselective benzylation of carbohydrate trans-diols

A convenient approach to regioselective benzylation of carbohydrate trans-diols was developed, where 0.1 equiv. of Bu2SnCl2 and 0.1 equiv. of TBABr were used as the catalysts and 2.0 equiv. of BnCl was used as the benzylation reagent. In most cases, similar or better benzylation regioselectivities and isolated yields were obtained by using catalytic amounts of Bu2SnCl2, rather than stoichiometric amounts of organotin reagents required.

Influence of O6 in mannosylations using benzylidene protected donors: Stereoelectronic or conformational effects?

The stereoselective synthesis of β-mannosides and the underlying reaction mechanism have been thoroughly studied, and especially the benzylidene-protected mannosides have gained a lot of attention since the corresponding mannosyl triflates often give exce