1422040-28-5

Basic information

• Product Name: (5S,8S)-8-((S)-1-(benzyloxy)allyl)-5-butyl-10,10,11,11-tetramethyl-2,4,9-trioxa-10-siladodec-6-yne
• Synonyms: (5S,8S)-8-((S)-1-(benzyloxy)allyl)-5-butyl-10,10,11,11-tetramethyl-2,4,9-trioxa-10-siladodec-6-yne
• CAS NO: 1422040-28-5
• Molecular Weight: 446.703
• Mol File: 1422040-28-5.mol

Chemical Properties

• CAS DataBase Reference: (5S,8S)-8-((S)-1-(benzyloxy)allyl)-5-butyl-10,10,11,11-tetramethyl-2,4,9-trioxa-10-siladodec-6-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (5S,8S)-8-((S)-1-(benzyloxy)allyl)-5-butyl-10,10,11,11-tetramethyl-2,4,9-trioxa-10-siladodec-6-yne(1422040-28-5)
• EPA Substance Registry System: (5S,8S)-8-((S)-1-(benzyloxy)allyl)-5-butyl-10,10,11,11-tetramethyl-2,4,9-trioxa-10-siladodec-6-yne(1422040-28-5)

Safety Data

• Hazardous Substances Data: 1422040-28-5(Hazardous Substances Data)

Upstream product

• 790695-76-0 (S)-(-)-3-methoxymethoxy-1-heptyne 
• 51703-66-3 (S)-(-)-1-heptyn-3-ol 
• 1422040-24-1 (3S,4S,7S)-3-(benzyloxy)-7-(methoxymethoxy)undec-1-en-5-yn-4-ol 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 1422040-29-6 (4S,5S,8S,Z)-methyl 4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-8-(methoxymethoxy)dodec-2-en-6-ynoate 
• 1422040-30-9 (5S,6S)-5-(benzyloxy)-6-((S)-3-hydroxyhept-1-ynyl)-5,6-dihydro-2H-pyran-2-one 
• 1422040-31-0 (5S,6S)-5-(benzyloxy)-6-((S,Z)-3-hydroxyhept-1-enyl)-5,6-dihydro-2H-pyran-2-one 
• 1422040-32-1 (S,Z)-1-((2S,3S)-3-(benzyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl)hept-1-en-3-yl acetate 

Relevant articles and documents

First stereoselective total synthesis of pectinolide C and total synthesis of pectinolide A

The first stereoselective synthesis of pectinolide C and synthesis of pectinolide A, from easily accessible 1-hexyne and d-mannitol are reported in a convergent manner. The salient features include acetylenic addition to the chiral aldehyde and Still-Genn