1422177-75-0Relevant academic research and scientific papers
Tandem reactions involving 1-silyl-3-boryl-2-alkenes. New access to (Z)-1-fluoro-1-alkenes, allyl fluorides, and diversely α-substituted allylboronates
MacE, Aurelie,Tripoteau, Fabien,Zhao, Qian,Gayon, Eric,Vrancken, Emmanuel,Campagne, Jean-Marc,Carboni, Bertrand
supporting information, p. 906 - 909 (2013/03/28)
The reactions of 1-silyl-3-boryl-2-alkenes with various electrophilic reagents (Selectfluor, N-halosuccinimides, benzhydryl, and propargylic alcohols in the presence of a Lewis acid, N-alkoxycarbonyliminium ion) have been investigated as new routes to α-substituted allylboronates. Further functional transformations, including allylboration, Suzuki coupling, protodeboronation, and cycloisomerization, have been carried out to illustrate the synthetic potential of these γ-borylallylsilanes.
