1422271-39-3Relevant academic research and scientific papers
Benzo[1,2-d:4,5-d']bisimidazoles as a convenient platform towards dyes that are capable of excited-state intramolecular proton transfer and of two-photon absorption
Tasior, Mariusz,Gryko, Daniel T.,Hugues, Vincent,Blanchard-Desce, Mireille
, p. 2656 - 2661,6 (2020/09/02)
New, strongly fluorescent benzo[1,2-d:4,5-d']bisimidazoles have been prepared by the reaction of Bandrowski's base with various aldehydes. Their structures were carefully designed to achieve efficient excited-state intramolecular proton transfer and good two-photon-absorption (2PA) cross-sections. Functional dyes that possessed both high fluorescence quantum yields and large Stokes shifts were prepared. A π-expanded D-A-D derivative that possessed φfl=50 % and σ2=230 GM in the spectroscopic area of interest for biological imaging is an excellent candidate as a fluorescent probe. Thanks to the presence of two reactive amino groups, such compounds can be easily transformed into probes for bioconjugation. All of these benzo[1,2-d:4,5-d']bisimidazoles were also strongly fluorescent in the solid state. Copyright
