1422469-25-7Relevant academic research and scientific papers
Stereo- And regio-selective synthesis of silicon-containing diborylalkenes: via platinum-catalyzed mono-lateral diboration of dialkynylsilanes
Long, Peng-Wei,Xie, Jia-Le,Yang, Jing-Jing,Lu, Si-Qi,Xu, Zheng,Ye, Fei,Xu, Li-Wen
, p. 4188 - 4191 (2020/04/22)
A highly chemoselective platinum-catalyzed mono-lateral diboration of dialkynylsilanes for the construction of silicon-tethered alkynyl diborylalkenes is described, in which tris(4-methoxyphenyl)phosphine was found to be an effective ligand for the cis-addition of diboron agents to the silicon-tethered alkynes, and the chiral ligand (AFSi-Phos)-mediated diboration of dialkynylsilanes resulted in the desymmetric construction of silicon-stereogenic centers with promising enantioselectivity.
Dehydrogenative silylation of terminal alkynes with hydrosilanes under zinc-pyridine catalysis
Tsuchimoto, Teruhisa,Fujii, Masakazu,Iketani, Yoshihiko,Sekine, Masaru
supporting information, p. 2959 - 2964 (2013/01/15)
A combination of zinc triflate and pyridine in a nitrile medium was found to act as an effective catalytic system for dehydrogenative silylation with flexible pieces of terminal alkynes and hydrosilanes, thereby producing diverse alkynylsilanes in high to
