1422584-38-0Relevant articles and documents
Reactions of 2-thioxoper hydro-1, 3-thiazin-4 ones with cyclopentadienyl - Ruthenium II, dicarbonyldichloro ruthenium II complexes and tetra carbonyldi-μ-halodirhodium
Singh,Singh,Singh
, p. 1425 - 1432 (2013/02/25)
In this paper, the reaction of 2-thioxopherhydro-1, 3-thiazine-4 ones with [Ru(η5-C5H5) (PPh3) 2X] (X=CI, Br, I), [Ru(η5--C5H5) (MPh3)2 CI] (M = As, Sb) and [Ru(CO)2 Cl 2] complexes lead to the formations of [Ru(η5-C 5H5) (PPh3) (TPH)X] (X=CI, Br, I), [Ru( 5-C5H5) (MPη3 (TPH) Cl] (M=As, Sb) [Ru(CO)2 CI2(TPH)] and [Rh(CO)2 X(TPH)] (X=CI, Br) The compounds have been characterised by analytical, magnetic, conductivity and spectroscopic (ir, uv and visible) studies and a quasioctahedral geometry is proposed for Ru(II) complexes and square planar geometry for Rh(I) Complexes.