1422722-64-2Relevant academic research and scientific papers
Copper-catalyzed benzylic oxidation of C(sp3)-H bonds
Zhang, Bo,Zhu, Shou-Fei,Zhou, Qi-Lin
, p. 2033 - 2037 (2013)
A selective oxidation of benzylic C(sp3)-H bonds to C(sp 3)-O bonds catalyzed by copper complexes of quinoline-imine ligands was developed with peresters as oxidants under mild reaction conditions, which converted benzylic methylenes directly into benzylic alcohols and esters by means of direct C-H bond functionalization.
Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2 N,N′}palladium(II) acetonitrile monosolvate
Motswainyana, William M.,Onani, Martin O.,Jacobs, Jeroen,Van Meervelt, Luc
, p. m356-m358 (2012)
The title complex, [PdCl2(C20H20N2)]·CH3CN, was synthesized by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline with dichlorido(cycloocta-1,5-diene)palladium(II) in dry CH2Cl2. The PdII ion is coordinated by two N atoms of the bidentate quinoline ligand and by two chloride anions, generating a distorted square-planar coordination geometry around the metal centre. There is a detectable trans influence for the chloride ligands. The crystal packing is characterized by π-π stacking between the quinoline rings. The use of acetonitrile as the crystallization solvent was essential for obtaining good-quality crystals.
Imino-quinolyl palladium(II) and platinum(II) complexes: Synthesis, characterization, molecular structures and cytotoxic effect
Motswainyana, William M.,Onani, Martin O.,Madiehe, Abram M.,Saibu, Morounke,Jacobs, Jeroen,Van Meervelt, Luc
, p. 197 - 202 (2013/07/31)
Imino-quinolyl ligands L1-L5 were synthesized by condensation reactions and obtained in good yields. Reactions of the ligands with either PdCl 2(cod) or K2[PtCl4] gave the corresponding palladium(II) and platinum(II) complexes 1-10 also in good yields. All the compounds were characterized by elemental analysis, IR, 1H and 13C NMR spectroscopy. X-ray crystallography was used to confirm the structures of these compounds. Molecular structures of 3 and 5 showed that the ligands coordinate to the metal center through the two nitrogen atoms, generating a distorted square planar geometry around the palladium atom. The new complexes exhibited remarkable cytotoxic activities against MCF-7 and HT-29 cancer cell lines.
