1422960-20-0Relevant articles and documents
Highly curved bowl-shaped fragments of fullerenes: Synthesis, structural analysis, and physical properties
Chen, Min-Kuan,Hsin, Hsin-Ju,Wu, Tsun-Cheng,Kang, Bo-Yan,Lee, Yen-Wei,Kuo, Ming-Yu,Wu, Yao-Ting
, p. 598 - 608 (2014/04/03)
Highly curved buckybowls 3, 4, and 5 were synthesized from planar precursors, fluoranthenes 8, benzo[k]- fluoranthenes 10 and naphtho[1,2-k]- cyclopenta[cd]fluoranthenes 12, respectively, using straightforward palladium-catalyzed cyclization reactions. Th
Bowl-shaped fragments of C70 or higher fullerenes: Synthesis, structural analysis, and inversion dynamics
Wu, Tsun-Cheng,Chen, Min-Kuan,Lee, Yen-Wei,Kuo, Ming-Yu,Wu, Yao-Ting
supporting information, p. 1289 - 1293 (2013/03/14)
Super bowl: Fragments of C70 or higher fullerenes were easily prepared from 1,8-bis(arylethynyl)naphthalenes. The curved structures were identified by X-ray crystallography. These rigid bowl-shaped molecules have a deep bowl depth (approximately 2.30 A) and their bowl inversions proceed via an S-shaped transition structure with a very high inversion barrier (approximately 80 kcal mol-1). Copyright