1422962-67-1Relevant academic research and scientific papers
6,6-Dicyanopentafulvenes: Teaching an old dog new tricks
Finke, Aaron D.,Diederich, Franois
, p. 19 - 30 (2015/03/04)
6,6-Dicyanopentafulvene (DCF) is a fascinating molecular entity that consists of a cyclopentadiene ring conjugated to an exocyclic double bond bearing two cyano groups on its periphery. Herein, we give a brief history of the chemistry of DCFs prior to our
Expanding the chemical structure space of opto-electronic molecular materials: Unprecedented push-pull chromophores by reaction of a donor-substituted tetracyanofulvene with electron-rich alkynes
Jayamurugan, Govindasamy,Dumele, Oliver,Gisselbrecht, Jean-Paul,Boudon, Corinne,Schweizer, W. Bernd,Bernet, Bruno,Diederich, Fran?ois
, p. 3599 - 3606 (2013/05/08)
The reaction of a 3,5-bis(N,N-dimethylanilino)-substituted 2,4,6,6-tetracyanopentafulvene (TCPF) with mono- and bis(N,N-dimethylanilino) acetylene provides facile access to push-pull chromophores with diverse new scaffolds. The starting TCPF reacts with b
