1422972-08-4

Basic information

• Product Name: 2-isopropyl-2-(2-methylphenyl)-2H-furo[3,2-g]chromene-3,7-dione
• Synonyms: 2-isopropyl-2-(2-methylphenyl)-2H-furo[3,2-g]chromene-3,7-dione
• CAS NO: 1422972-08-4
• Molecular Weight: 334.372
• Mol File: 1422972-08-4.mol

Chemical Properties

• CAS DataBase Reference: 2-isopropyl-2-(2-methylphenyl)-2H-furo[3,2-g]chromene-3,7-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-isopropyl-2-(2-methylphenyl)-2H-furo[3,2-g]chromene-3,7-dione(1422972-08-4)
• EPA Substance Registry System: 2-isopropyl-2-(2-methylphenyl)-2H-furo[3,2-g]chromene-3,7-dione(1422972-08-4)

Safety Data

• Hazardous Substances Data: 1422972-08-4(Hazardous Substances Data)

Upstream product

• 133-26-6 peucedanin 
• 32898-70-7 oreoselone 
• 16419-60-6 2-Methylphenylboronic acid 

Relevant articles and documents

Plant coumarins: XI. Cross coupling reactions with 2-(tosyl)oreoselone

The reaction of a linearly fused furocoumarin, oreoselone, with p-toluenesulfonyl chloride gave 2-tosyloreoselone which showed a high reactivity in palladium-catalyzed cross-coupling reactions with formation of a new carbon-carbon bond. 2-Tosyloreoselone reacted with terminal alkynes in the presence of Pd(PPh3)2Cl2 to give the corresponding 2-alkynylfuro[3,2-g]chromen-3-ones. 2-Aryl(hetaryl) alkynyloreoselones were obtained in high yield directly by palladium-catalyzed reaction of oreoselone with tosyl chloride and aryl(hetaryl)acetylenes. The reaction of 2-tosyloreoselone with aryl(hetaryl)boronic acids in the presence of palladium complexes with uni- and bidentate ligands, tetrabutylammonium bromide, and a base afforded 2-aryl(hetaryl)-substituted oreoselones. 2-Vinyloreoselone was synthesized from 2-tosyloreoselone and potassium trifluoro(vinyl)borate.