1423-08-1

Basic information

• Product Name: 1,3,5-trifluoro(2,4,6-d3)benzene
• CAS NO: 1423-08-1
• Molecular Weight: 135.061
• Mol File: 1423-08-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3,5-trifluoro(2,4,6-d3)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-trifluoro(2,4,6-d3)benzene(1423-08-1)
• EPA Substance Registry System: 1,3,5-trifluoro(2,4,6-d3)benzene(1423-08-1)

Safety Data

• Hazardous Substances Data: 1423-08-1(Hazardous Substances Data)

Upstream product

• 372-38-3 1,3,5-trifluorobenzene 

Relevant articles and documents

Thermoneutral Isotope Exchange Reactions of Cations in the Gas Phase

Rate constants have been measured for reactions of the type AD2+ + MH --> MD + ADH+, where AD2+ is CD3CND+, CD3CDOD+, (CD3COCD3)D+, or (C2D5)2OD+ and the MH molecules are alcohols, acids, mercaptanes, H2S, AsH3, PH3, or aromatic molecules.Rate constants are also presented for the reactions ArHD+ + D2O --> ArDD+ + HDO, where ArHD+ is a deuteronated aromatic molecule and ArDD+ is the same species with a D atom incorporated on the ring.In all but two cases, the competing deuteron transfer is sufficiently endothermic that it cannot be observed under the conditions of the ICR experiments at 320 - 420 K.The efficiencies of the isotope exchange reactions are interpreted in terms of estimated potential surface cross sections for the reactions AD2+ + MH --> 2+*MH> --> +> --> +*MD> --> ADH+ + MD.When the formation of the +> complex is estimated to be thermoneutral or slightly endothermic, the isotope exchange process is inefficient (probability of a reactive collision 2+*MH> --> +> is exothermic.For most of the systems, trends in reaction efficiency appear to be related to factors such as dipole moments of reactant species (or for aromatic compounds, the electron-donating or -withdrawing properties of ring substituents) which influence the relative orientation of the two reactant species in the complex.