1423-18-3Relevant articles and documents
Hexacoordinated Sulfur(VI) and Ψ-Hexacoordinated Sulfur(IV) Anions
Heilemann, Werner,Mews, Ruediger,Pohl, Siegfried,Saak, Wolfgang
, p. 427 - 432 (2007/10/02)
(Me2N)3S+OSF5- (3) was prepared from OSF4 and (Me2N)3S+Me3SiF2- ("TAS fluoride ", 1).From 1 and SF4, CF3SF3, and (CF2)2CFSF3, TAS+SF5- (5a), TAS+CF3SF4- (5b), and TAS+(CF3)2CFSF4- (5c) were obtained.Spectroscopic data of these salts and the crystal structure of 3 are reported. - Keywords: Pentafluorooxosulfate ion/ Sulfur anions, fluorine-containing/ Sulfur tetrafluoride derivatives/ Tris(dimethylamino)sulfonium difluorotrimethylsilicate