142316-24-3Relevant academic research and scientific papers
Syntheses and Structures of , , (L = N2 or CO) and
Dilworth, Jonathan R.,Hu, Jin,Miller, John R.,Hughes, David L.,Zubieta, Jon A.,Chen, Qin
, p. 3153 - 3164 (2007/10/03)
The hydride reacted with 2,6-dimethylbenzenethiol in toluene to give a complex of stoichiometry 1.A crystal structure showed a trigonal-bipyramidal geometry about the Re with an agostic interaction to a thiolate methyl occupying an apical site, trans to the PPh3 ligand.Complex 1 reacts rapidly with MeCN to give the known 2 and with t-BuNC to form 3.The crystal structure of 3 showed trigonal-pyramidal geometry about the Re with asymmetric co-ordination of the isocyanide ligands and an unusual configuration for the thiolate aromatic groups.The reactions of the hydrides and with 2,4,6-triisopropyl-, 2,6-dimethoxy-benzenethiol and tris(2-sulfanylphenyl)phosphine were also studied.With HSC6H2(i-Pr)3-2,4,6 the dinitrogen complex 4 was formed and its structure determined.The preparations and structures of the complexes , 3(PPh3)> and (PPh3)> are also discussed.An alternative convenient route to (+) from is presented.
A d4-Thiolato-Dinitrogen Complex. The Synthesis and Crystal Structure of
Dilworth, Jonathan R.,Hu, Jin,Thompson, Russell M.,Hughes, David L.
, p. 551 - 553 (2007/10/02)
or reacted with L in toluene, under dinitrogen, to give and , respectively in good yield, and under similar
