142340-45-2Relevant academic research and scientific papers
Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (R)-BINAP ligand
Han, Difei,Li, Xiaohong,Zhang, Huidong,Liu, Zhimin,Hu, Gengshen,Li, Can
, p. 15 - 22 (2008)
Rhodium nanoparticles have been conveniently synthesized by one-pot chemical reduction of aqueous rhodium chloride (RhCl3·3H2O) dispersed in toluene solution in the presence of amphiphilic tetraoctylammonium bromide (TOAB) and chiral
Synthesis and Rh-catalyzed reductive cyclization of 1,6-enynes and 1,6-diynes containing alkynylboronate termini
Ozerov, Oleg V.,Pell, Christopher J.
supporting information, (2020/02/20)
Ir-catalyzed dehydrogenative borylation of terminal alkynes (DHBTA) has been used to borylate the C(sp)-H bond in a series of 1,6-enynes and 1,6-diynes. Ir catalysts based on the diarylamido/bis(phosphine) PNP ligands proved to be capable of performing DH
Rhodium-catalyzed stereoselective formation of Z-enamines from allylaziridines
Alphonse, France-Aimee,Yudin, Andrei K.
, p. 11754 - 11755 (2007/10/03)
Rhodium (I)-catalyzed isomerization of N-allylaziridines affords isolable Z-enamines in excellent yields and with high stereoselectivity. Cationic [Rh(BINAP)(COD)]OTf and RhH(CO)(PPh3)3 follow the same selectivity toward the Z-isomer
