1423757-87-2Relevant academic research and scientific papers
A formal metal-free N-arylation via the Schmidt reaction of aromatic aldehydes with an azido amine
Gu, Peiming,Sun, Jian,Kang, Xiao-Yan,Yi, Ming,Li, Xue-Qiang,Xue, Ping,Li, Rui
, p. 1124 - 1127 (2013/04/10)
A formal metal-free N-arylation of aromatic aldehydes with 3-azido-N-tosylpropan-1-amine through the Schmidt process was realized in the presence of acids. TfOH was found to be a good promoter, and the exclusive 1,2-aryl migration was observed. Furthermor
