142389-63-7

Upstream product

• 30889-20-4 methyl cyclohexa-2,5-diene-1-carboxylate 
• 142389-62-6 methyl 1-(4,4-dimethoxybutyl)-2,5-cyclohexadiene-1-carboxylate 

Downstream Products

• 142389-64-8 methyl 1-<4-<<(trifluoromethyl)sulfonyl>oxy>-3(Z)-butenyl>-2,5-cyclohexadiene-1-carboxylate 
• 142389-64-8 methyl 1-<4-<<(trifluoromethyl)sulfonyl>oxy>-3(E)-butenyl>-2,5-cyclohexadiene-1-carboxylate 
• 142389-65-9 Trifluoro-methanesulfonic acid (Z)-4-[1-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-but-1-enyl ester 
• 152327-05-4 2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester 
• 142389-66-0 Acetic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester 
• 142389-68-2 Trifluoro-methanesulfonic acid (Z)-4-(1-hydroxymethyl-cyclohexa-2,5-dienyl)-but-1-enyl ester 

Relevant academic research and scientific papers

Effects of solvents and additives in the asymmetric heck reaction of alkenyl triflates: Catalytic asymmetric synthesis of decalin derivatives and determination of the absolute stereochemistry of (+)-vernolepin

Studies on the palladium-catalyzed asymmetric cyclization of alkenyl triflates 3 including the effects of S solvents and additives such as alcohol and potassium acetate on the reaction are described. Reaction of 3 in polar solvents such as DMSO, acetonitr

Further studies on a catalytic asymmetric synthesis of decalin derivatives

The decalin derivatives 2 (92% ee) and 18c (92% ee) were synthesized from the corresponding prochiral substrates 7b and 17a by an asymmetric Heck reaction.