142407-30-5Relevant academic research and scientific papers
Microbiological and chemical methods in the asymmetric oxidation of sulfides: A comparative study for the preparation of (S)-vinyl sulfoxides
Rossi,Fauve,Madesclaire,Roche,Davis,Reddy
, p. 629 - 636 (2007/10/02)
The enantiogenicity of biological and chemical oxidation at the sulfur atom was studied on a series of prochiral vinyl sulfides for the preparation of sulfoxides of (S)-absolute configuration. Using either fungal cultures, Sharpless-modified reagent or chiral oxaziridine, the enantiomeric excesses varied according to the substrate's steric and/or electronic structure; the three methods were complementary.
