142435-66-3

Upstream product

• 792910-34-0 C₂₀H₃₀O₅Si 
• 792910-35-1 Acetic acid (1R,2S,6R)-4-(tert-butyl-dimethyl-silanyloxymethyl)-5-oxo-7-oxa-bicyclo[4.1.0]hept-3-en-2-yl ester 
• 792910-36-2 (1R,5S,6R)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxy-7-oxa-bicyclo[4.1.0]hept-3-en-2-one 
• 174156-50-4 (2R,3S,4S)-4-tert-butyldimethylsilyloxy-2,3-epoxy-6-hydroxymethyl-5-cyclohexen-1-one 
• 1391563-99-7 C₁₄H₂₂O₃Si 
• 1391563-95-3 C₁₃H₂₂O₄Si 
• 1391563-94-2 C₁₃H₂₄O₄Si 
• 1391563-91-9 C₁₉H₃₆O₄Si₂ 
• 313547-95-4 (3R,4R,5R)-3-[(tert-butyl-dimethylsilyl)oxy]-4,5-(isopropylidenedioxy)-1-cyclohexanone 
• 74293-60-0 (3aR,7R,7aS)-7-hydroxy-2,2-dimethyltetrahydrobenzo[d][1,3]dioxol-5(6H)-one 
• 188308-06-7 (2R,3S,4S)-4-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxy-6-iodo-5-cyclohexen-1-one 
• 188308-05-6 (2R,3S,4S)-4-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxy-5-cyclohexen-1-one 
• 188308-08-9 (2R,3S,4S)-4-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxy-6-(3-methylbut-3-en-1-ynyl)-5-cyclohexen-1-one 

Relevant academic research and scientific papers

Enantioselective syntheses of bioactive epoxyquinone natural products (+)-harveynone and (-)-asperpentyn

Stereo- and enantioselective syntheses of (+)-harveynone and (-)-asperpentyn are reported.

The First Synthesis of (-)-Asperpentyn and Efficient Syntheses of (+)-Harveynone, (+)-Epiepoformin and (-)-Theobroxide

A generally applicable strategy for the synthesis of a range of polyoxygenated cyclohexane natural products has been developed. The enantioselective syntheses of (-)-theobroxide, a polyoxygenated cyclohexane natural compound with potent growth inducing pr

Absolute configuration of (+)-PT-toxin: Enantiodivergent synthesis of (+)- and (-)-PT-toxins

Absolute configuration of (+)-PT-toxin, isolated from the tea gray blight fungi, Pestalotiopsis longiseta and Pestalotiopsis theae, has been determined unambiguously by enantiocontrolled synthesis of both enantiomers starting from the common chiral-building block.