14248-23-8Relevant articles and documents
The Stabilized Cation Pool Method: Metal- and Oxidant-Free Benzylic C-H/Aromatic C-H Cross-Coupling
Hayashi, Ryutaro,Shimizu, Akihiro,Yoshida, Jun-Ichi
, p. 8400 - 8403 (2016/07/27)
Electrochemical oxidation of toluene derivatives in the presence of a sulfilimine gave benzylaminosulfonium ions as stabilized benzyl cation pools, which reacted with subsequently added aromatic nucleophiles to give the corresponding cross-coupling produc
Trialkylsilyl triflimides as easily tunable organocatalysts for allylation and benzylation of silyl carbon nucleophiles with non-genotoxic reagents
Mendoza, Oscar,Rossey, Guy,Ghosez, Léon
supporting information; experimental part, p. 2571 - 2575 (2010/06/21)
Trialkylsilyl triflimides generated in situ are unique catalysts for the electrophilic benzylation or allylation of trialkylsilylenol ethers or allyl trialkylsilanes with non-genotoxic alkylating reagents such as benzyl and allyl acetates. In most cases the reactions are fast at room temperature and yields are high. The reaction works particularly well with electron-rich benzyl donors including derivatives of pyrrole, indole and furane.
Coupling reaction of alkyl chlorides with silyl enolates catalyzed by indium trihalide
Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
, p. 4931 - 4934 (2008/03/27)
Indium(III) halide catalyzed not only the coupling of alkyl chlorides with silyl enolates derived from esters, ketones, and aldehydes to give a variety of α-alkylated carbonyl compounds but also one-pot, three-component reactions of aldehyde enolate, alkyl chloride, and allylsilane or alkynylsilane.