1425040-83-0Relevant articles and documents
Chiral gold complex-catalyzed hetero-diels-alder reaction of diazenes: Highly enantioselective and general for dienes
Liu, Bin,Li, Kang-Nan,Luo, Shi-Wei,Huang, Jian-Zhou,Pang, Huan,Gong, Liu-Zhu
supporting information, p. 3323 - 3326 (2013/04/23)
A chiral gold(I) complex-catalyzed highly regio- and enantioselective azo hetero-Diels-Alder reaction has been developed. The chiral gold(I) complex acting as a Lewis acid exhibits high efficiency in the activation of urea-based diazene dienophiles. Moreover, this chiral gold catalyst also rendered a cascade intramolecular enyne cycloisomerization/asymmetric azo-HDA reaction.