142576-58-7Relevant academic research and scientific papers
Synthesis and Dioxygen-binding Properties of Double-sided Porphyrinatoiron(II) Complexes bearing Covalently Bound Axial Imidazole
Tsuchida, Eishun,Komatsu, Teruyuki,Arai, Kenji,Nishide, Hiroyuki
, p. 2465 - 2469 (2007/10/02)
Double-sided porphyrinatoiron(II) complexes bearing covalently bound axial imidazole, 5--10,15,20-trisporphyrinatoiron(II) and 5-2-(3,3-dimethylbutyryloxy)-6-(5-imidazolylvaler
Double-Sided Porphyrinatoiron(II) Bearing Covalently Bound Imidazole. An Efficient Oxygen-Carrier Molecule Composed by 8 Ester Bonds
Komatsu, Teruyuki,Arai, Kenji,Nishide, Hiroyuki,Tsuchida, Eischun
, p. 799 - 802 (2007/10/02)
Double-sided porphyrinatoiron(II) bearing covalently bound axial imidazole, 5,10,15-tris(2,6-bis(3,3-dimethylbutyryloxy)phenyl)-20-(2-(3,3-dimethylbutyryloxy)-6-(5-imidazolylvaleroyloxy)phenyl)porphyrinatoiron (1b), was synthesized: The substituents of 1b are bound with the porphyrin only through ester bonds. 1b formed a stable O2 adduct reversibly in toluene at 25 deg C or with a lipid surfactant under physiological conditions.
