1426-66-0 Usage
Uses
Used in Chemical Synthesis:
TRIBUTYL(PENTAFLUOROETHYL)STANNANE is used as a reagent for the stannylation of cyclopropenes to yield stannylcyclopropenes. These stannylcyclopropenes are key building blocks for the synthesis of substituted cyclopropenes, which are important intermediates in the production of various pharmaceuticals and organic compounds.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, TRIBUTYL(PENTAFLUOROETHYL)STANNANE is used as a synthetic intermediate for the development of new drugs. The stannylcyclopropenes derived from TRIBUTYL(PENTAFLUOROETHYL)STANNANE can be further modified and functionalized to create novel drug candidates with potential therapeutic applications.
Used in Organic Chemistry Research:
TRIBUTYL(PENTAFLUOROETHYL)STANNANE is also utilized in academic and industrial research settings for the exploration of new synthetic pathways and the development of innovative chemical reactions. Its unique reactivity allows chemists to access a wide range of complex molecular structures that may have applications in various fields, including materials science, agrochemistry, and environmental chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 1426-66-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,4,2 and 6 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1426-66:
(6*1)+(5*4)+(4*2)+(3*6)+(2*6)+(1*6)=70
70 % 10 = 0
So 1426-66-0 is a valid CAS Registry Number.
InChI:InChI=1/3C4H9.C2F5.Sn/c3*1-3-4-2;3-1(4)2(5,6)7;/h3*1,3-4H2,2H3;;/rC14H27F5Sn/c1-4-7-10-20(11-8-5-2,12-9-6-3)14(18,19)13(15,16)17/h4-12H2,1-3H3
1426-66-0Relevant academic research and scientific papers
Method for Producing Fluorine-Containing Substituted Compound and Fluorine-Containing Substituted Compound
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Paragraph 0255-0272, (2014/02/15)
A method for producing a fluorine-containing substituted compound, the method including: introducing an organofluorine compound and an organolithium compound into a microreactor provided with a flow path capable of mixing a plurality of liquids, to thereby obtain a reaction product; and introducing, into the microreactor, the reaction product and an electrophile exhibiting electrophilic effect on the reaction product, to thereby obtain a fluorine-containing substituted compound.
Perfluoroalkylation in flow microreactors: Generation of perfluoroalkyllithiums in the presence and absence of electrophiles
Nagaki, Aiichiro,Tokuoka, Shinya,Yamada, Shigeyuki,Tomida, Yutaka,Oshiro, Kojun,Amii, Hideki,Yoshida, Jun-Ichi
, p. 7559 - 7563 (2011/12/03)
Perfluoroalkyllithiums were effectively generated from perfluoroalkyl halides in the presence and absence of electrophiles using flow microreactor systems. The in situ trapping with electrophile is conducted at much higher temperatures than those required for batch macro reactors. The subsequent trapping method is quite effective for highly reactive electrophiles that are not compatible with the lithiation process.
