1426147-68-3Relevant academic research and scientific papers
Simple and clean synthesis of ketones from internal olefins using PdCl 2/N,N-dimethylacetamide catalyst system
Mitsudome, Takato,Yoshida, Syuhei,Tsubomoto, Yamato,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
supporting information, p. 1596 - 1598 (2013/03/14)
A simple catalytic system consisting of PdCl2 and N,N-dimethylacetamide enabled clean and selective synthesis of ketones from internal olefins using molecular oxygen. Various functionalized internal olefins were directly and regioselectively oxidized; C atoms of CC bonds far from substituted moieties were preferably oxidized.
