1426317-27-2Relevant academic research and scientific papers
Enantioselective total syntheses of plectosphaeroic acids B and C
Jabri, Salman Y.,Overman, Larry E.
, p. 8766 - 8788 (2013/09/24)
Evolution of the synthetic strategy that culminated in the first total syntheses of the structurally unique plectosphaeroic acids B (2) and C (3) is described. The successful enantioselective route to (+)-2 and (+)-3 proceeds in 6 and 11 steps from the kn
Enantioselective total synthesis of plectosphaeroic acid B
Jabri, Salman Y.,Overman, Larry E.
supporting information, p. 4231 - 4234 (2013/05/21)
The first total synthesis of a member of the plectosphaeroic acid family of fungal natural products is reported. Key steps include the late-stage formation of the hindered N6-C9″ bond and stereoselective introduction of the two methylthio substituents.
