1426341-81-2

Upstream product

• 615-42-9 1,2-Diiodobenzene 
• 1426342-06-4 (3S,3aS)-5,5-dibutyl-3a-hydroxymethyl-3-phenyl-2-tosyl-1,2,3,3a,4,5-hexahydrostannolo[3,4-c]pyrrole 
• 17763-91-6 1,2-bis-trifluoromethanesulfonyloxybenzene 
• 583-53-9 2,3-dibromobenzene 
• 1383438-14-9 (3S,3aS)-tert-butyl 5,5-dibutyl-3-phenyl-2-tosyl-1,2,3,3a,4,5-hexahydrostannolo[3,4-c]pyrrole-3a-carboxylate 

Relevant academic research and scientific papers

A regioselective double Stille coupling reaction of bicyclic stannolanes

A regioselective double Stille coupling reaction was explored using bicyclic stannolanes that were easily prepared from the radical cascade reaction of β-amino-α-methylene esters. Various 1-bromo-2-iodoarenes underwent the double coupling reaction to affo

Pd-catalyzed tandem sp2-sp3 coupling reactions of chiral stannolanes: An efficient preparation of optically active tetrahydrobenz[f]isoindoles

A novel double Migita-Kosugi-Stille coupling reaction with dihydrostannolanes, which are readily available from a radical cascade reaction, was achieved with dihalobenzenes in the presence of a palladium catalyst. Use of unsymmetrical 1-bromo-2-iodobenzene derivatives accomplished the double coupling reaction which gave tetrahydrobenz[f]isoindoles in a regioselective manner.