142635-23-2Relevant academic research and scientific papers
Stereoselective C-glycoside formation by a rhodium(I)-catalyzed 1,4-addition of arylboronic acids to acetylated enones derived from glycals
Ramnauth, Jailall,Poulin, Odile,Bratovanov, Svetoslav S.,Rakhit, Suman,Maddaford, Shawn P.
, p. 2571 - 2573 (2007/10/03)
(Equation presented) A new method for the formation of C-glycosides has been developed employing a cationic rhodium(l)-catalyzed 1,4-addition of arylboronic acids to enones derived from glycals. The reaction is stereoselective for the α-anomer and is highly dependent on the nature of the rhodium catalyst.
Palladium-Mediated Arylation of Acetylated Enones Derived from Glycals. 4. Synthesis of Aryl 2-Deoxy-β-D-C-glycopyranosides
Benhaddou, Rachida,Czernecki, Stanislas,Ville, Guy
, p. 4612 - 4616 (2007/10/02)
The palladium-mediated arylation of the peracetylated glycal-derived enones 1, 2, and 3 afforded mixtures of C-glycosides containing an arylated enone (1a, 2a, or 3a) and an arylated ketone (1b, 2 b, or 3b).A rationale for the formation of these compounds
