142656-50-6Relevant articles and documents
New Perrhenates and Aminorhenium Trioxides with Elements of Group 14. and 15. of the Periodic System
Wirringa, Uwe,Roesky, Herbert W.,Schmidt, Hans-Georg,Noltemeyer, Mathias
, p. 2359 - 2362 (2007/10/02)
New perrhenates have been prepared by reaction of Re2O7 with triphenylstibin oxide and di-n-butyltin oxide, respectively.The single-crystal X-ray structure of Ph3Sb(OReO3)2 (1) is reported.The reaction of Ph3SbO and nBu2SnO with Re2O7 in 1:2 molar ratio gives (O3ReOSbPh3)2O (2) and 2O (3), respectively.A trimethylstannyl-substituted aminorhenium trioxide (Me3Sn)2NReO3 (4) has been prepared by reaction of Me3SiOReO3 and N(SnMe3)3.Key Words: Rhenium(VII) compounds / Organooxides of elements of group 14 and 15