1426585-77-4

Basic information

• Product Name: pinacol (R)-1-N-sulfinylphenylmethyl-1-boronate
• CAS NO: 1426585-77-4
• Molecular Weight: 351.318
• Mol File: 1426585-77-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: pinacol (R)-1-N-sulfinylphenylmethyl-1-boronate(CAS DataBase Reference)
• NIST Chemistry Reference: pinacol (R)-1-N-sulfinylphenylmethyl-1-boronate(1426585-77-4)
• EPA Substance Registry System: pinacol (R)-1-N-sulfinylphenylmethyl-1-boronate(1426585-77-4)

Safety Data

• Hazardous Substances Data: 1426585-77-4(Hazardous Substances Data)

Upstream product

• 73183-34-3 bis(pinacol)diborane 
• 212378-97-7 (R(S))-N-(1-phenylethylidene)-tert-butanesulfinamide 

Relevant articles and documents

Improving carbene-copper-catalyzed asymmetric synthesis of α-aminoboronic esters using benzimidazole-based precursors

By using a benzimidazole core and N-substitutions to tune the electronic properties of the corresponding N-heterocyclic carbenes, a one-pot protocol for efficient synthesis of α-aminoboronic esters without the need of a glovebox was developed in this work. The starting materials for the transformation can also be extended from aldehydes to ketones. An alternative protocol with short reaction time using preformed carbene-copper chloride is also described.