142668-07-3Relevant academic research and scientific papers
THERMOLYSIS OF 3,6-DIAZA- AND 6-AZA-3-OXABENZOTRICYCLO2,4>-OCTANES: FORMATION OF NOVEL 4,1-BENZOXAZOCINES
Kurita, Jyoji,Kikuchi, Katsuhiro,Aruga, Toshiko,Tsuchiya, Takashi
, p. 685 - 688 (2007/10/02)
Thermolysis of the 3,6-diazabenzotricyclo2,4>octane (7) at 180 deg C resulted in rearrangement to give the pyrroloindole (9), whereas flash vacuum pyrolysis of the 6-aza-3-oxabenzotricyclooctanes (8) at 530 deg C resulted in both ring-expansion and rearrangement to afford the novel 4,1-benzoxazocines (10) and furoindoles (11).
