142671-85-0Relevant academic research and scientific papers
Catalytic activity of dodecacarbonyltetracobalt in aqueous media: A "greening" of the Pauson-Khand reaction
Bonaga, Llorente V. R.,Wright, James A.,Krafft, Marie E.
, p. 1746 - 1747 (2004)
The unprecedented reactivity of Co4(CO)12 with enynes under aqueous conditions, representing the development of a mild and simple aqueous-phase cobalt-catalyzed PK reaction protocol, is described herein.
Pauson-khand reactions in water
Krafft, Marie E.,Wright, James A.,Bonaga, Llorente V.R.
, p. 1006 - 1016 (2007/10/03)
We have investigated the cobalt mediated Pauson-Khand (PK) reaction in water. In the presence of detergents and surfactants, Co2(CO) 8 and Co4(CO)12 are effective under aqueous-phase, thermal PK reactions. In a
Dimethyldioxirane in organometallic chemistry. II. An improved procedure for the oxidative decomplexation of Fischer carbene complexes
Lluch,Jordi,Sanchez-Baeza,Ricart,Camps,Messeguer,Moreto
, p. 3021 - 3022 (2007/10/02)
Treatment of Fischer carbene complexes 1 with dimethyldioxirane affords good conversion yields of the corresponding oxo derivatives 2, in a clean and highly chemoselective reaction.
Pauson-Khand Reaction with Electron-Deficient Alkynes
Krafft, Marie E.,Romero, Romulo H.,Scott, Ian L.
, p. 5277 - 5278 (2007/10/02)
Cobalt carbonyl complexes of electron-deficient internal alkynes undergo Pauson-Khand cycloaddition efficiently and regioselectively.
