1426853-75-9Relevant academic research and scientific papers
Bioinspired construction of a spirocyclohexadienone moiety via sodium nitrite catalyzed aerobic intramolecular oxidative phenol coupling
Su, Bo,Deng, Meng,Wang, Qingmin
supporting information, p. 1606 - 1609 (2013/06/27)
An efficient and green intramolecular oxidative phenol coupling for the direct construction of spirocyclohexadienones has been developed, which uses environment-friendly sodium nitrite as the catalyst and oxygen in the air as the terminal oxidant. Hydroxy-containing substituted phenanthrenes and dibenzoazepines could be easily obtained from the dienone-phenol rearrangement.
