1426919-11-0Relevant articles and documents
Synthesis and photophysical properties of 3,5-diaryl-2-heteroarylthiophenes
Karpavi?ien?, Ieva,Jonu?is, Mantas,Leduskrasts, Kaspars,Misiūnait?, Indr?,Suna, Edgars,?ikotien?, Inga
, (2019)
A series of 3,5-diaryl-2-heteroarylthiophenes have been synthesized via Fiesselmann type reaction between alkynones and easily available heteroarylmethanethiols or heteroarylmethyl carbamimidothioates. A correlation between compounds structure and efficie
Pd-catalyzed selective carbonylative and non-carbonylative couplings of propiolic acid: One-pot synthesis of diarylalkynones
Kim, Wonyoung,Park, Kyungho,Park, Ahbyeol,Choe, Juseok,Lee, Sunwoo
supporting information, p. 1654 - 1657 (2013/06/26)
Diarylalkynones were synthesized from one-pot Pd-catalyzed carbonylative and noncarbonylative coupling reactions of propiolic acid with aryl iodides under a carbon monoxide atmosphere. Aryl iodide (2.0 equiv), propiolic acid (1.0 equiv), Pd(PPh3)2Cl2 (5 mol %), CuCl (10 mol %), Et3N (6.0 equiv), and CO (8 atm) were reacted under optimized conditions in CH3CN at 80 °C for 1 h. This process afforded good yields and functional group tolerance.