1427182-87-3Relevant academic research and scientific papers
Zinc-catalyzed Meinwald rearrangement of tetrasubstituted 1-alkynyloxiranes to tertiary α-alkynylketones
Gonzalez, Maria J.,Gonzalez, Jesus,Perez-Calleja, Carmela,Lopez, Luis A.,Vicente, Ruben
, p. 932 - 934 (2013)
Easy access to tertiary α-alkynylketones via a Meinwald-type rearrangement of 1-alkynyloxiranes is reported. This transformation is selectively accomplished with an economical zinc catalyst.
