142719-06-0Relevant articles and documents
P-Methoxybenzyl-N-phenyl-2,2,2-trifluoroacetimidate: A versatile reagent for mild acid catalyzed etherification
Barroca-Aubry, Nadine,Benchekroun, Mohamed,Gomes, Filipe,Bonnaffé, David
supporting information, p. 5118 - 5121 (2013/09/02)
PMB-NPTFA 1a is a new month bench stable and powerful reagent for the formation of PMB ethers. Several alcohols were protected in high yields and short reaction times, using low reagent loading and small catalytic amounts of Bi(OTf)3. The mild
Reverse orthogonal strategy for oligosaccharide synthesis
Fujikawa, Kohki,Ganesh, N. Vijaya,Tan, Yih Horng,Stine, Keith J.,Demchenko, Alexei V.
supporting information; experimental part, p. 10602 - 10604 (2011/11/06)
Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction.