142730-73-2Relevant academic research and scientific papers
Allylsilanes in Organic Synthesis; Double Asymmetric Induction in the Dihydroxylation of a Chiral Allylsilane.
Ward, Richard A.,Procter, Garry
, p. 12821 - 12836 (2007/10/02)
The diastereoselectivity of the dihydroxylation of ester-allylsilanes, particularly stereoisomers of methyl E-2-methyl-3-(phenyldimethylsilyl)hept-4-enoate, has been studied; the diastereoselectivity can be increased by using potassium ferricyanide as the
Allylsilanes in organic synthesis: Highly stereoselective alkylation of β-silyl-α-lactones
Daly, Matthew J.,Procter, Carry
, p. 7549 - 7550 (2007/10/02)
Direct alkylation of hydroxy-lactones obtained by the diastereoselective dihydroxylation of ester-allylsilanes takes place with high diastereoselectivity without protection of the hydroxyl function.
Allylsilanes in Organic Synthesis; Double Asymmetric Induction in the Dihydroxylation of a Chiral Allylsilane.
Ward, Richard A.,Procter, Garry
, p. 3363 - 3366 (2007/10/02)
Double asymmetric induction has been used to increase the diastereoselectivity of the dihydroxylation of the allylsilane (+)-(11) using dihydroquinidine p-chlorobenzoate as catalyst. Key words: Allylsilanes; dihydroxylation; enantioselective catalysis; ki
