1427318-07-7

Basic information

• Product Name: C₁₀H₁₀Cl₂S
• Synonyms: C₁₀H₁₀Cl₂S
• CAS NO: 1427318-07-7
• Molecular Weight: 233.161
• Mol File: 1427318-07-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₀H₁₀Cl₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₀H₁₀Cl₂S(1427318-07-7)
• EPA Substance Registry System: C₁₀H₁₀Cl₂S(1427318-07-7)

Safety Data

• Hazardous Substances Data: 1427318-07-7(Hazardous Substances Data)

Upstream product

• 1391948-77-8 ((4-chlorophenyl)ethynyl)(ethyl)sulfane 

Downstream Products

• 1427318-38-4 C₁₆H₁₅ClS 

Relevant articles and documents

An operationally simple approach to (E)-α-halo vinyl sulfides and their applications for accessing stereodefined trisubstituted alkenes

An operationally simple and practical protocol for the synthesis of (E)-α-halo vinyl sulfides has been achieved via a highly regio- and stereoselective hydrohalogenation of alkynyl thioethers using lithium halides in HOAc or propionic acid at room temperature. It permits the formation of (E)-α-chloro and (E)-α-bromo vinyl sulfides in satisfactory yields with good to excellent stereoselectivities. Moreover, this work results in a new method for the assembly of stereodefined (E)- or (Z)-trisubstituted alkenes featuring the first coupling of the C-X bond of (E)-α-halo vinyl sulfides followed by a subsequent Ni-catalyzed coupling of the C-S bond with Grignard reagents. The Royal Society of Chemistry 2013.