1427439-23-3

Basic information

• Product Name: 4-bromo-2-hydroxy-3-methoxy benzaldehyde
• Synonyms: 4-bromo-2-hydroxy-3-methoxy benzaldehyde
• CAS NO: 1427439-23-3
• Molecular Weight: 231.046
• Mol File: 1427439-23-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-bromo-2-hydroxy-3-methoxy benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-2-hydroxy-3-methoxy benzaldehyde(1427439-23-3)
• EPA Substance Registry System: 4-bromo-2-hydroxy-3-methoxy benzaldehyde(1427439-23-3)

Safety Data

• Hazardous Substances Data: 1427439-23-3(Hazardous Substances Data)

Upstream product

• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 

Downstream Products

• 1612223-68-3 C₂₇H₂₉ClN₄O₄ 
• 1612223-64-9 4-bromo-3-(3-chlorophenoxy)-2-methoxybenzaldehyde 
• 1612223-66-1 C₁₇H₁₈BrClO₅S 
• 1612223-76-3 2-(3-chlorophenoxy)-3-methoxy-4-{(1R)-1-[(3S)-3-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)piperidin-1-yl]propyl}benzoic acid 
• 1612223-77-4 2-(3-chlorophenoxy)-3-methoxy-4-{(1S)-1-[(3S)-3-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)piperidin-1-yl]propyl}benzoic acid 
• 1612223-69-4 2-(3-chlorophenoxy)-3-methoxy-4-{1-[(3S)-3-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)piperidin-1-yl]propyl}benzoic acid 
• 1612223-67-2 1-[(3S)-1-{1-[4-bromo-3-(3-chlorophenoxy)-2-methoxyphenyl]propyl}piperidin-3-yl]-5-methylpyrimidine-2,4(1H,3H)-dione 
• 1612223-65-0 1-[4-bromo-3-(3-chlorophenoxy)-2-methoxyphenyl]propan-1-ol 

Relevant articles and documents

Synthesis, characterization, crystal structure, catalytic activity in oxidative bromination, and thermal study of a new oxidovanadium Schiff base complex containing O, N-bidentate Schiff base ligand

A new oxidovanadium(IV) Schiff base complex, VOL2 (1), HL = 2-{(E)-[2-(bromoethyl)imino]methyl}-6-methoxy phenol, containing ethyl bromide pendant group was synthesized by direct reaction of HL and VO(acac)2 in the ratio of 2: 1 in methanol at reflux. The Schiff base ligand and its vanadyl complex were characterized by FT-IR spectra and CHN analysis. Additionally, the Schiff base ligand has been characterized by 1H NMR spectroscopy. The crystal structure of 1 was also determined by single-crystal X-ray analysis, showing the distorted square-pyramidal N2O3 coordination around vanadium(IV). The catalytic activity of 1 was studied in the oxidative bromination of 2-nitrophenol as a model substrate, and different reaction parameters were investigated. The oxidative bromination of some organic compounds in the presence of 1 in optimal conditions showed that it was an effective and selective catalyst in those optimal conditions. Thermogravimetric analysis of 1 showed that it decomposed in two stages. 1 was thermally decomposed in air at 660 °C, and the XRD pattern of the obtained solid showed the formation of the V2O5 nanoparticles with average size of 34 nm.