14277-07-7

Upstream product

• 540-23-8 p-toluidine hydrochloride 
• 140-29-4 phenylacetonitrile 
• 645-54-5 2-phenylthioacetamide 
• 106-49-0 p-toluidine 
• 99-99-0 1-methyl-4-nitrobenzene 

Downstream Products

• 37134-94-4 2-benzyl-5-methylbenzimidazole 
• 37134-94-4 2-benzyl-6-methyl-1H-benzo[d]imidazole 
• 97627-41-3 [3-Benzyl-2-p-tolyl-2H-[1,2,4]thiadiazol-(5E)-ylidene]-phenyl-amine 
• 74115-85-8 6-Amino-5-phenyl-4-p-tolyl-2-p-tolylamino-nicotinonitrile 
• 74115-84-7 6-Amino-4,5-diphenyl-2-p-tolylamino-nicotinonitrile 
• 74115-75-6 2-Amino-6-imino-5-phenyl-1,4-di-p-tolyl-1,6-dihydro-pyridine-3-carbonitrile 
• 74115-74-5 2-Amino-6-imino-4,5-diphenyl-1-p-tolyl-1,6-dihydro-pyridine-3-carbonitrile 
• 1190715-91-3 (2,6-bis(methylsulphanyl)-5-phenyl[1,3]thiazin-4-ylidene)-p-tolylamine 
• 1190715-87-7 2-methylsulphanyl-5-phenyl-4-p-tolylamino[1,3]thiazine-6-thione 
• 1190715-93-5 2,N-bis([1,3]dithian-2-ylidene)-2-phenyl-N'-p-tolylacetamidine 
• 1190715-89-9 2-ethylsulphanyl-5-phenyl-4-p-tolylamino[1,3]thiazine-6-thione 

Relevant academic research and scientific papers

Practical Synthesis of Benzimidazo[1,2- A[quinolines via Rh(III)-Catalyzed C-H Activation Cascade Reaction from Imidamides and Anthranils

We report a novel and practical one-pot Rh(III)-catalyzed strategy to construct benzimidazo[1,2-a]quinolines from readily available imidamides and anthranils. The cascade reaction proceeds via a C-H amination-cyclization-cyclization process in ionic liquid without any additives and possesses simple operation, moderate-to-high yield, and broad substrate scope features, which will provide the reference for the construction of biologically active fused benzimidazoles.

Synthesis of indoles and quinazolines via additive-controlled selective C-H activation/annulation of N -arylamidines and sulfoxonium ylides

Selective synthesis of indole and quinazoline products was achieved through a precise control of the C-H activation/annulation by changing the additives from NaOAc to CuF2/CsOAc. This strategy constructs indole and quinazoline scaffolds efficie

Samarium(II) iodide induced reductive coupling of nitriles with nitro compounds

The intermolecular and intramolecular reductive coupling of a cyano group with a nitro group induced by SmI2 was studied. Amidines and 2-aminoquinoline derivatives are prepared in good yields under neutral and mild conditions respectively.

Facile Synthesis of Amidines via the Intermolecular Reductive Coupling of Nitriles with Nitro Compounds Induced by Samarium(II) Iodide

The intermolecular reductive coupling of nitriles with nitro compounds induced by Sml2 was studied; amidine derivatives are prepared in good yields under neutral and mild conditions.

Low-valent titanium induced reductive coupling of nitriles with nitro compounds

The intermolecular and intramolecular reductive coupling of a cyano group with a nitro group induced by a low-valent titanium reagent prepared from TiCl4/Sm was studied. Amidines and 2-aminoquinolines derivatives are prepared in good yields under mild conditions respectively.