14277-17-9Relevant academic research and scientific papers
Cross-metathesis reactions as an efficient tool in the synthesis of fluorinated cyclic β-amino acids
Fustero, Santos,Sanchez-Rosello, Maria,Acena, Jose Luis,Fernandez, Begona,Asensio, Amparo,Sanz-Cervera, Juan F.,Del Pozo, Carlos
supporting information; experimental part, p. 3414 - 3423 (2009/09/26)
The synthesis of enantiomerically pure, cyclic, γ,γ- difluorinated β-amino acids with various ring sizes has been carried out with a cross-metathesis (CM) reaction being one of the key steps, followed by a Dieckmann-type condensation to bring about the cy
METATHESIS OF FUNCTIONAL DERIVATIVES OF OLEFINS BY THE ACTION OF THE WCl6-1,1,3,3-TETRAMETHYL-1,3-DISILACYCLOBUTANE CATALYTIC SYSTEM
Bespalova, N. B.,Bovina, M. A.
, p. 156 - 159 (2007/10/02)
A study was carried out on the metathesis of esters of unsaturated carboxylic acids and nitriles by the action of the WCl6-1,1,3,3-tetramethyl-1,3-disilacyclobutane catalytic system.The possibility of efficient homometathesis and cometathesis with α-olefins and allyltrimethylsilane was demonstrated for ethyl 4-pentenoate and allyl cyanide.
