1427772-64-2Relevant academic research and scientific papers
Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents
Zang, Yu,Nakao, Kazuki,Yotsuyanagi, Hiroki,Aoki, Toshiki,Namikoshi, Takeshi,Tsutsuba, Toyokazu,Teraguchi, Masahiro,Kaneko, Takashi
, p. 1729 - 1733 (2013/04/24)
By using a new achiral phenylacetylene having bulky substituents as a monomer, living-like helix-sense-selective polymerization (HSSP) has been achieved. This is the first example of the HSSP of substituted acetylenes where the degree of polymerization was controlled. The resulting one-handed helical living polymer initiated polymerization of a second monomer to successfully yield a block copolymer.
