1427777-83-0

Basic information

• Product Name: C₁₄H₁₂ClF₃O₅S
• Synonyms: C₁₄H₁₂ClF₃O₅S
• CAS NO: 1427777-83-0
• Molecular Weight: 384.76
• Mol File: 1427777-83-0.mol

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₂ClF₃O₅S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₂ClF₃O₅S(1427777-83-0)
• EPA Substance Registry System: C₁₄H₁₂ClF₃O₅S(1427777-83-0)

Safety Data

• Hazardous Substances Data: 1427777-83-0(Hazardous Substances Data)

Upstream product

• 29805-11-6 1-(4-chlorophenyl)prop-2-yn-1-ol 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Relevant articles and documents

Subtle electronic effects in metal-free rearrangement of allenic alcohols

A general and stereoselective rearrangement of allenic alcohols to (E,E)-1,3-dien-2-yl triflates and chlorides was developed under metal-free conditions. Subtle electronic effects of the alkyl and aryl substituents on the carbon bearing the hydroxyl group has a profound impact on the reaction rate and efficiency such that vinyl triflates were obtained from electron-deficient substrates and trimethylsilyl triflate whereas vinyl chlorides were generated with an electron-rich substrate and trimethylsilyl chloride.