142779-27-9Relevant academic research and scientific papers
Dramatic reversal of enantioselectivity in β-aminoalcohol-catalyzed addition of diethylzinc to aldehydes
Kimura,Sugiyama,Ishizuka,Kunieda
, p. 3147 - 3150 (1992)
β-Aminoalcohols sterically constrained by a dibenzobicyclo[2.2.2] ring system serve well as chiral catalysts in highly enantioselective additions of diethylzinc to aldehydes (up to 98% e.e.). A dramatic reversal of the enantioselectivity is observed when
